Tetrahedron Letters p. 4869 - 4872 (1986)
Update date:2022-07-29
Topics:
Negishi, Ei-ichi
Tour, James M.
Treatment of o-iodoaryl alkenyl ketones with CO (600 psi) in CH3CN in the presence of 5 mol percent of Pd(dba)2 and 1 equiv of NEt3 can give bicyclic and polycyclic quinones in high yields via acylpalladation in an "endo" mode, which appears to be totally
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