1092770-71-2Relevant academic research and scientific papers
Remarkable synergistic effect between MonBI and MonBII on epoxide opening reaction in ionophore polyether monensin biosynthesis
Sato, Kyohei,Minami, Atsushi,Ose, Toyoyuki,Oguri, Hiroki,Oikawa, Hideaki
, p. 5277 - 5280 (2011)
Enzymatic epoxide-opening cascade is one of the key biosynthetic processes for constructing structurally diverse polyethers. Here we report the first in vitro analysis of the cyclization catalyzed by two epoxide hydrolases, MonBI and MonBII involved in mo
Conversion of allylic alcohols to stereodefined trisubstituted alkenes: A complementary process to the claisen rearrangement
Belardi, Justin K.,Micalizio, Glenn C.
body text, p. 16870 - 16872 (2009/04/13)
A stereoselective method for the conversion of allylic alcohols to (Z)-trisubstituted alkenes is presented. Overall, the reaction sequence described is stereochemically complementary to related Claisen rearrangement reactions □ processes that typically deliver the stereoisomeric trisubstituted alkene containing products. Copyright
