1092969-79-3Relevant academic research and scientific papers
Tunable chiral reaction media based on two-component liquid crystals: Regio-, diastereo-, and enantiocontrolled photodimerization of anthracenecarboxylic acids
Ishida, Yasuhiro,Achalkumar, Ammathnadu S.,Kato, Shun-Ya,Kai, Yukiko,Misawa, Aya,Hayashi, Yumi,Yamada, Kuniyo,Matsuoka, Yuki,Shiro, Motoo,Saigo, Kazuhiko
scheme or table, p. 17435 - 17446 (2011/02/27)
Three kinds of enantiopure amphiphilic amino alcohols (1a-c) were newly synthesized, of which the stereochemistry of the stereogenic carbons adjacent to the amino (C2) and hydroxy (C1) groups was systematically varied. By using these amino alcohols and fo
Two-component liquid crystals as chiral reaction media: Highly enantioselective photodimerization of an anthracene derivative driven by the ordered microenvironment
Ishida, Yasuhiro,Kai, Yukiko,Kato, Syun-Ya,Misawa, Aya,Amano, Sayaka,Matsuoka, Yuki,Saigo, Kazuhiko
supporting information; experimental part, p. 8241 - 8245 (2009/04/13)
(Chemical Equation Presented) Tailored to the reaction: Within a liquid-crystalline matrix provided by a chiral amphiphilic amino alcohol, the photodimerization of an anthracenecarboxylic acid proceeds with high probability and with excellent regio-, diastereo-, and enantioselectivities (up to 81% ee).
