1092970-80-3Relevant academic research and scientific papers
The first chemoselective tandem acylation of the Blaise reaction intermediate: A novel method for the synthesis of α-acyl-β-enamino esters, key intermediate for pyrazoles
Sung Chun, Yu,Kon Lee, Ki,Ok Ko, Young,Shin, Hyunik,Lee, Sang-Gi
supporting information; experimental part, p. 5098 - 5100 (2009/03/11)
The Blaise reaction intermediate, a zinc bromide complex of β-enamino ester, could be activated in situ by addition of a stoichiometric or catalytic amount of n-BuLi to allow chemoselective tandem C2-acylation providing α-acyl-β-enamino esters, which are
