1093076-02-8Relevant articles and documents
Novel substituted 1-iminoisoindoline derivatives: Synthesis, structure determination and antiproliferative activity
Sovi?, Irena,Stilinovi?, Vladimir,Kaitner, Branko,Kraljevi?-Paveli?, Sandra,Bujak, Maro,?uljak, Katarina,Novak, Predrag,Karminski-Zamola, Grace
, p. 259 - 265 (2011)
Novel derivatives of isoindoline, N-phenyl-1-iminophenylisoindoline 6, N-(4-methylphenyl)-1-imino-(4-methylphenyl)-isoindoline 7, N-(pyridin-2-yl)-1- imino-(pyridin-2-yl)-isoindoline 8 and N-(5-methylpyridin-2-yl)-1-imino(5- methylpyridin-2-yl)-isoindolin
Synthesis of palladacycles employing iminoisoindolines as monoanionic bidentate ligands
Chitanda, Jackson M.,Prokopchuk, Demyan E.,Quail, J. Wilson,Foley, Stephen R.
experimental part, p. 6023 - 6029 (2009/02/08)
A series of air- and moisture-stable iminoisoindoline-based palladacycles have been prepared in two operationally simple steps from commercially available reagents. para-Substituted N,N′-diphenyliminoisoindoline ligands are easily synthesized from phthalaldehyde and para-substituted anilines and further reaction of the iminoisoindoline ligands with Pd(OAc)2 in dichloromethane at room temperature results in formation of six-membered [C,N] dinuclear cyclopalladated complexes with the general formula [(iminoisoindoline)Pd(μ-OAc)]2. The resulting palladacyclic complexes were tested as precatalysts in Heck and Suzuki coupling reactions.