109328-47-4Relevant academic research and scientific papers
Radical mechanism in the elimination of 2-arylsulfinyl esters
Latorre, Antonio,Lopez, Irakusne,Ramirez, Victoria,Rodriguez, Santiago,Izquierdo, Javier,Gonzalez, Florenci V.,Vicent, Cristian
experimental part, p. 5191 - 5197 (2012/07/27)
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction.
Synthesis of α-Phenylthio Enones and Esters of α-Phenylthio Alkenoic Acids
Durman, John,Grayson, J.Ian,Hunt, Paul G.,Warren, Stuart
, p. 1939 - 1946 (2007/10/02)
The title compounds can be made by a Pummerer dehydration from the corresponding saturated sulphoxides.The alkylation of anions from saturated and unsaturated ketones is described.
ALKYLATION OF EXTENDED ENOLATES FROM α-PHENYLTHIO CROTONATE ESTERS
Durman, John,Hunt, Paul G.,Warren, Stuart
, p. 2113 - 2116 (2007/10/02)
Conditions are described for the formation of enolate anions from substituted α-phenylthio-crotonate esters and their alkylation at the α-carbon atom.
