1093649-22-9Relevant academic research and scientific papers
New pyridine N-oxides as chiral organocatalysts in the asymmetric allylation of aromatic aldehydes
Malkov, Andrei V.,Westwater, Mary-Margaret,Gutnov, Andrey,Ramírez-López, Pedro,Friscourt, Frédéric,Kadl?íková, Aneta,Hoda?ová, Jana,Rankovic, Zoran,Kotora, Martin,Ko?ovsky, Pavel
experimental part, p. 11335 - 11348 (2009/04/11)
Asymmetric allylation of aromatic aldehydes 1 with allyltrichlorosilane (2) can be catalyzed by new terpene-derived bipyridine N,N′-dioxides 12-15 and an axially chiral biisoquinoline dioxide 17b with good enantioselectivities. Dioxides have been found to be more reactive catalysts than their monooxide counterparts. Crown Copyright
