19890-00-7

Basic information

• Product Name: Bicyclo[3.1.1]heptan-3-one, 6,6-dimethyl-2-methylene-, (1S,5S)-
• Synonyms: pin-2(10)-en-3-one;(1S,5S)-6,6-Dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-one;(2S,5S)-6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptan-3-one;pinocarvone;(1R)-6,6-dimethyl-2-methylenebicyclo[3.1.1]hept-3-one;(1S,5S)-6,6-dimethyl-2-methylenebicyclo[3.1.1]heptan-3-one;Bicyclo[3.1.1]heptan-3-one, 6,6-dimethyl-2-methylene-, (1S)-;6,6-dimethyl-2-methylenebicyclo[3.1.1]heptan-3-one
• CAS NO: 19890-00-7
• Molecular Formula: C10H14O
• Molecular Weight: 150.221
• Mol File: 19890-00-7.mol
• Article Data: 3

Chemical Properties

• Melting Point: -0.9°C
• Boiling Point: 60 - 62 °C (3 - 5 mmHg)
• Density: 0.9875
• Refractive Index: 1.4950
• CAS DataBase Reference: Bicyclo[3.1.1]heptan-3-one, 6,6-dimethyl-2-methylene-, (1S,5S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[3.1.1]heptan-3-one, 6,6-dimethyl-2-methylene-, (1S,5S)-(19890-00-7)
• EPA Substance Registry System: Bicyclo[3.1.1]heptan-3-one, 6,6-dimethyl-2-methylene-, (1S,5S)-(19890-00-7)

Safety Data

• Hazardous Substances Data: 19890-00-7(Hazardous Substances Data)

Upstream product

• 7664-93-9 sulfuric acid 
• 144-62-7 oxalic acid 
• 1674-08-4 3-hydroxy-β-pinene 
• 1010824-89-1 (1S,5R)-2-(chloromethyl)-6,6-dimethyl-bicyclo[3.3.1]hept-2-ene 
• 65861-96-3 (+)-3-chloro-2⁽¹⁰⁾-pinene 
• 14575-92-9 2,3-epoxy-cis-pinane 

Downstream Products

• 19889-99-7 (+)-(Z)-pinocarveol 
• 1674-08-4 (-)-trans-pinocarveol 
• 473-62-1 (1R,2R,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-one 
• 328242-17-7 (1S,9S)-5-(2-methoxyphenyl)-10,10-dimethyl-6-azatricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene 
• 409319-21-7 (1S,9S)-(+)-5-(2-fluorophenyl)-10,10-dimethyl-6-azatricyclo[7.1.1.0^2,7]undeca-2⁽⁷⁾,3,5-triene 
• 1093649-22-9 (1S,9S)-(+)-10,10-dimethyl-5-[3'-(pyridin-2''-yl)phenyl]-6-aza-tricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene 
• 1093649-21-8 C₂₃H₂₂N₂ 
• 211874-85-0 (1S,9S)-10,10-dimethyl-5-phenyl-6-azatricyclo[7.1.1.0 ^2,7]undeca-2,4,6-triene 
• 1585185-98-3 C₄₀H₄₄N₂O 
• 1585185-99-4 2,2'-(propane-2,2-diyl)bis(6,6-dimethyl-5,6,7,8-tetrahydro-5,7-methanoquinoline-8,2-diyl)bis(diphenylmethanol) 
• 1448527-32-9 (+)-5-(3’,4’,5’-trimethoxyphenyl)-8,10,10-trimethyl-6-azatricyclo[7.1.1.02,7]undeca-2,4,6-triene 6-oxide 
• 561280-12-4 C₁₉H₂₀FNO 
• 561280-14-6 C₂₀H₂₃NO₂ 
• 561280-11-3 C₁₉H₂₁NO 

Relevant articles and documents

Synthesis and reactions of organic compounds with a nitrogen atom. Part XV. Reactions of (+)-3-chloro-2(10)-pinene and (-)-10-chloro-2-pinene with phenyltelluro- and phenylselenosodium

Toluenesulfonamidation of (+)-3-chloro-2(10)-pinene (4) and (-)-10-chloro-2-pinene (5) with phenylselenosodium (2) or phenyltellurosodium (3) and chloramine-T gave exclusively N-trans-[2′(10′) pinen-3′-yl]toluenesulfonamide (7). Oxidation of 10-phenylseleno-2-pinene (6) and 10-phenyltelluro-2-pinene (12) prepared from the chlorides 4 and 5 was examined. The reduction of toluenesulfonamide 7 with sodium in liquid ammonia gave (+)-trans-3-amino-2(10)-pinene (8).

TERPENOIDS FROM THE FRENCH LIVERWORT TARGIONIA HYPOPHYLLA

Key Word Index - Targionia hypophylla; Targioniaceae; Hepaticae; cis- and trans-pinocarveyl acetates; mono-, sesqui- and diterpenoids.Two monoterpene acetates, cis- and trans-pinocarveyl acetates, which make up the characteristic aroma of the thalloid liverwort Targionia hypophylla were isolated, together with the previously known sesquiterpene alcohol, drimenol.