19890-00-7

Upstream product

• 14575-92-9 2,3-epoxy-cis-pinane 
• 65861-96-3 (+)-3-chloro-2⁽¹⁰⁾-pinene 
• 1010824-89-1 (1S,5R)-2-(chloromethyl)-6,6-dimethyl-bicyclo[3.3.1]hept-2-ene 
• 1674-08-4 3-hydroxy-β-pinene 
• 7664-93-9 sulfuric acid 
• 144-62-7 oxalic acid 

Downstream Products

• 19889-99-7 (+)-(Z)-pinocarveol 
• 1674-08-4 (-)-trans-pinocarveol 
• 473-62-1 (1R,2R,5S)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-one 
• 503433-64-5 (4RS,6S,8S)-4-benzyloxy-6,8-methano-7,7-dimethyl-1,2,3,4,5,6,7,8-octahydroacridine 
• 1093649-22-9 (1S,9S)-(+)-10,10-dimethyl-5-[3'-(pyridin-2''-yl)phenyl]-6-aza-tricyclo[7.1.1.0(2,7)]undeca-2⁽⁷⁾,3,5-triene 
• 1093649-21-8 C₂₃H₂₂N₂ 
• 211874-85-0 (1S,9S)-10,10-dimethyl-5-phenyl-6-azatricyclo[7.1.1.0 ^2,7]undeca-2,4,6-triene 
• 1674-08-4 3-hydroxy-β-pinene 
• 21725-97-3 6,6-dimethyl-3'-phenyl-4'H-spiro[bicyclo[3.1.1.]heptane-2,5'-isoxazol]-3-one 
• 1448527-32-9 (+)-5-(3’,4’,5’-trimethoxyphenyl)-8,10,10-trimethyl-6-azatricyclo[7.1.1.02,7]undeca-2,4,6-triene 6-oxide 
• 561280-12-4 C₁₉H₂₀FNO 
• 561280-14-6 C₂₀H₂₃NO₂ 
• 561280-11-3 C₁₉H₂₁NO 
• 1448527-72-7 (+)-5-(3’,4’,5’-trimethoxyphenyl)-8,10,10-trimethyl-6-azatricyclo[7.1.1.02,7]undeca-2(7),3,5-triene 

Relevant academic research and scientific papers

Synthesis and reactions of organic compounds with a nitrogen atom. Part XV. Reactions of (+)-3-chloro-2(10)-pinene and (-)-10-chloro-2-pinene with phenyltelluro- and phenylselenosodium

Toluenesulfonamidation of (+)-3-chloro-2(10)-pinene (4) and (-)-10-chloro-2-pinene (5) with phenylselenosodium (2) or phenyltellurosodium (3) and chloramine-T gave exclusively N-trans-[2′(10′) pinen-3′-yl]toluenesulfonamide (7). Oxidation of 10-phenylseleno-2-pinene (6) and 10-phenyltelluro-2-pinene (12) prepared from the chlorides 4 and 5 was examined. The reduction of toluenesulfonamide 7 with sodium in liquid ammonia gave (+)-trans-3-amino-2(10)-pinene (8).

Part II: Transformations of α and β-Pinene Oxides over Binary Oxide Catalysts of Alumina-Rare Earth Oxides

The catalytic activity of binary oxides of Al2O3-Eu2O3, Al2O3-Sm2O3, Al2O3-NdO3, Al2O3-Pr6O11, and Al2O3-Y2O3 were checked in the transformations of α and β-pinene oxides.Al2O3-Eu2O3 and Al2O3-Nd2O3 are found to be best catalysts for α-pinene oxide isomeriztion.Among the oxiranes, α-pinene oxide showed more activity mainly yielding 2,2,3-trimethyl cyclopentene-1-acetaldehyde. β-pinene oxide produced trans-myrtanal and myrtanol.

TERPENOIDS FROM THE FRENCH LIVERWORT TARGIONIA HYPOPHYLLA

Key Word Index - Targionia hypophylla; Targioniaceae; Hepaticae; cis- and trans-pinocarveyl acetates; mono-, sesqui- and diterpenoids.Two monoterpene acetates, cis- and trans-pinocarveyl acetates, which make up the characteristic aroma of the thalloid liverwort Targionia hypophylla were isolated, together with the previously known sesquiterpene alcohol, drimenol.