1093663-02-5

Basic information

• Product Name: (7R,9S)-10-(tert-butyldiphenylsilyloxy)dec-5-yne-1,7,9-triol
• Synonyms: (7R,9S)-10-(tert-butyldiphenylsilyloxy)dec-5-yne-1,7,9-triol
• CAS NO: 1093663-02-5
• Molecular Weight: 440.655
• Mol File: 1093663-02-5.mol

Chemical Properties

• CAS DataBase Reference: (7R,9S)-10-(tert-butyldiphenylsilyloxy)dec-5-yne-1,7,9-triol(CAS DataBase Reference)
• NIST Chemistry Reference: (7R,9S)-10-(tert-butyldiphenylsilyloxy)dec-5-yne-1,7,9-triol(1093663-02-5)
• EPA Substance Registry System: (7R,9S)-10-(tert-butyldiphenylsilyloxy)dec-5-yne-1,7,9-triol(1093663-02-5)

Safety Data

• Hazardous Substances Data: 1093663-02-5(Hazardous Substances Data)

Upstream product

• 73448-13-2 tert-butyldimethylsilyl hex-5-yn-1-yl ether 
• 157758-30-0 (S)-3-((tert-butyldimethylsilyl)oxy)-4-((tert-butyldiphenylsilyl)oxy)butanal 
• 1093663-71-8 (6S,8R)-6-((tert-butyldimethylsilyl)oxy)-2,2,16,16,17,17-hexamethyl-3,3-diphenyl-4,15-dioxa-3,16-disilaoctadec-9-yn-8-ol 

Downstream Products

• 1093662-98-6 ((2S,6S)-1,7-dioxaspiro[5.5]undec-4-en-2-ylmethoxy)(tert-butyl)diphenylsilane 
• 1093663-04-7 (2S,4R,5S)-2-((tert-butyldiphenylsilyloxy)methyl)-1,6-dioxaspiro[4.6]undecan-4-ol 
• 1093663-06-9 (2S,4R,5R)-2-((tert-butyldiphenylsilyloxy)methyl)-1,6-dioxaspiro[4.6]undecan-4-ol 

Relevant articles and documents

Controlling regiochemistry in the gold-catalyzed synthesis of unsaturated spiroketals

A novel gold-catalyzed synthesis of unsaturated spiroketals that addresses regioselectivity issues commonly reported in metal-catalyzed spiroketalization of alkynes is reported. The reaction sequence is regulated by an acetonide protecting group which und

Au-catalyzed cyclization of monopropargylic triols: An expedient synthesis of monounsaturated spiroketals

The gold-catalyzed cyclization of monopropargylic triols to form olefin-containing spiroketals is reported. The reactions are rapid and high yielding when 2 mol % of the catalyst generated in situ from Au[P(t-Bu) 2(o-biphenyl)]CI and AgOTf is e