1094072-15-7 Usage
Uses
Used in Organic Synthesis:
3-Methoxy-2-(tributylstannyl)pyridine is used as a reagent for the introduction of the tributylstannyl group into organic molecules, which is crucial for the synthesis of complex organic compounds. The tributylstannyl group's ability to be easily converted into other functional groups makes 3-Methoxy-2-(tributylstannyl)pyridine a key component in the creation of diverse organic molecules.
Used in Organometallic Chemistry:
In organometallic chemistry, 3-Methoxy-2-(tributylstannyl)pyridine is utilized for its tributylstannyl group, which is significant for its conversion into various functional groups. This property is essential for the development of new organometallic compounds and materials.
Used in Selective Functionalization:
3-Methoxy-2-(tributylstannyl)pyridine is used as a directing group in certain chemical reactions, allowing for the selective functionalization of the pyridine ring. This selective approach is vital for the precise synthesis of target molecules with specific desired properties.
Used in Pharmaceutical and Agrochemical Industries:
3-Methoxy-2-(tributylstannyl)pyridine is employed as a building block in the synthesis of pharmaceuticals and agrochemicals, where its ability to introduce the tributylstannyl group and facilitate selective functionalization contributes to the development of new drugs and pesticides with improved efficacy and selectivity.
Used in Material Science:
In material science, 3-Methoxy-2-(tributylstannyl)pyridine is used in the synthesis of new materials with unique properties, such as conductive polymers, sensors, and other advanced materials, leveraging its role in organometallic chemistry and its ability to be selectively functionalized.
Check Digit Verification of cas no
The CAS Registry Mumber 1094072-15-7 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,9,4,0,7 and 2 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1094072-15:
(9*1)+(8*0)+(7*9)+(6*4)+(5*0)+(4*7)+(3*2)+(2*1)+(1*5)=137
137 % 10 = 7
So 1094072-15-7 is a valid CAS Registry Number.
1094072-15-7Relevant academic research and scientific papers
Synthesis of 2-(2-Pyridyl)-2 H-azirines via Metal-Free C-C Cross-Coupling of Bromoazirines with 2-Stannylpyridines
Agafonova, Anastasiya V.,Smetanin, Ilia A.,Rostovskii, Nikolai V.,Khlebnikov, Alexander F.,Novikov, Mikhail S.
supporting information, p. 8045 - 8049 (2021/10/20)
A high-yield method for the introduction of a 2-pyridyl substituent in the C2 position of the three-membered ring of 2-bromo-2H-azirine-2-carboxylic acid derivatives by the direct cross-coupling with 2-(trialkylstannyl)pyridines has been described. The reaction works well with 3-, 4-, or 5-substituted 2-stannylpyridines and can be also employed for the synthesis of 2-(thiazol-2-yl)-2H-azirines. According to DFT calculations, the reaction proceeds through the sequence of SN2′-substitution of bromine, 1,4-stannyl shift, and [2,3]-sigmatropic shift of the pyridine ring.
