1094455-93-2Relevant academic research and scientific papers
Iron(III) chloride catalyzed oxidative coupling of aromatic nuclei (Joc The Journal of Organic Chemistry (2004) 6 (913-916))
Wang, Kailiang,Lue, Maoyun,Zhu, Xiaoqing,Wang, Qingmin
supporting information; experimental part, p. 935 - 938 (2009/06/20)
Easily available and nontoxic FeCl3 catalyzes. intramolecular oxidative coupling for the direct construction of the phenan- threne ring using meta-chloroperbenzoic acid as sole oxidant at room temperature in excellent yields. The mechanistic investigations show that FeCl3-catalyzed coupling proceeds through the heterolytic coupling (A+ + B). The catalytic approach has been applied to intermolecular biaryl coupling of 2-naphthols and phenol ether.
