109467-74-5Relevant academic research and scientific papers
Palladium-catalyzed cross coupling of Grignard reagents with in situ-derived enol phosphates
Miller, Joseph A.
, p. 7111 - 7114 (2002)
A useful, one-pot protocol has been developed for the conversion of enolizable ketones to alkylated or arylated olefins by Pd-catalyzed cross coupling of in situ-generated enol phosphate intermediates with Grignard reagents.
Process for preparing vinylaromatic compounds
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, (2008/06/13)
The present invention provides a process for preparing a vinylaromatic compound comprising reacting an arylmetal reagent selected from arylmagnesium reagents and aryllithium reagents with a vinylphosphate in the presence of a palladium catalyst. The present invention also provides a process for preparing a vinylphosphate comprising reacting an enolizable ketone with a sterically hindered Grignard reagent and a halophosphate diester.
Nickel-catalyzed cross-couplings of cyclohexenyl phosphate and arylboronic acids
Nan, Yang,Yang, Zhen
, p. 3321 - 3324 (2007/10/03)
The Nickel-catalyzed cross-coupling reaction of cyclohexenylphosphate with a variety of arylboronic acids is described here for the first time. This methodology opens the door to other palladium or nickel-catalyzed coupling reactions involving vinyl phosphates.
Synthesis of β-Keto Phosphonates from Vinyl Phosphates via a 1,3-Phosphorus Migration
Calogeropoulou, Theodora,Hammond, Gerald B.,Wiemer, David F.
, p. 4185 - 4190 (2007/10/02)
A new method for the preparation of β-keto phosphonates has been developed, involving rearrangement of vinyl phosphates upon treatment with strong base.Because this approach ultimately relies upon electrophilic dialkyl phosphorochloridates as the phosphor
