20758-60-5

Basic information

• Product Name: Anisole, p-1-cyclohexen-1-yl-
• Synonyms: Anisole, p-1-cyclohexen-1-yl-;1-(1-Cyclohexenyl)-4-methoxybenzene;1-Methoxy-4-(1-cyclohexenyl)benzene;4-(1-Cyclohexene-1-yl)-1-methoxybenzene;4-(1-Cyclohexenyl)anisole;p-(1-Cyclohexenyl)anisole;1-(cyclohexen-1-yl)-4-methoxybenzene
• CAS NO: 20758-60-5
• Molecular Formula: C₁₃H₁₆O
• Molecular Weight: 188.2655
• Mol File: 20758-60-5.mol
• Article Data: 35

Chemical Properties

• Melting Point: 37 °C
• Boiling Point: 288.2°Cat760mmHg
• Flash Point: 111.3°C
• Appearance: /
• Density: 1.012g/cm³
• Vapor Pressure: 0.0041mmHg at 25°C
• Refractive Index: 1.54
• CAS DataBase Reference: Anisole, p-1-cyclohexen-1-yl-(CAS DataBase Reference)
• NIST Chemistry Reference: Anisole, p-1-cyclohexen-1-yl-(20758-60-5)
• EPA Substance Registry System: Anisole, p-1-cyclohexen-1-yl-(20758-60-5)

Safety Data

• Hazardous Substances Data: 20758-60-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H16O/c1-14-13-9-7-12(8-10-13)11-5-3-2-4-6-11/h5,7-10H,2-4,6H2,1H3

Upstream product

• 17138-79-3 1-(4-methoxyphenyl)cyclohexanol 
• 108-94-1 cyclohexanone 
• 100-66-3 methoxybenzene 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 709-08-0 1-(4-hydroxyphenyl)-1-cyclohexene 
• 77-78-1 dimethyl sulfate 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 696-62-8 para-iodoanisole 
• 110-83-8 cyclohexene 
• 5720-07-0 4-methoxyphenylboronic acid 
• 109467-74-5 phosphoric acid cyclohex-1-enyl ester diphenyl ester 
• 843-55-0 1,1-bis(p-hydroxyphenyl)cyclohexane 
• 1058146-79-4 C₁₇H₂₆O₂Si 
• 7570-92-5 cyclohexyl phenyl sulphide 

Downstream Products

• 5537-76-8 6-(4-methoxyphenyl)-6-oxohexanoic acid 
• 65662-61-5 1-[1-(Fluoro-dinitro-methyl)-2-nitro-cyclohexyl]-4-methoxy-benzene 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 74326-72-0 N-Hydroxy-N-[2-(4-methoxy-phenyl)-cyclohex-2-enyl]-acetamide 
• 52689-06-2 exo-6-(4-Anisyl)bicyclo<3.1.1>heptan-endo-6-ol 
• 129353-32-8 1-(4'-Methoxyphenyl)-7-methylenebicyclo<4.1.0>heptane 
• 127047-36-3 3-thiocyanato-2-(4-methoxyphenyl)cyclohexene 
• 37087-68-6 2-(4-methoxyphenyl)cyclohexanone 
• 101471-06-1 2-azido-1-iodo-1-(4-methoxyphenyl)cyclohexane 

Relevant articles and documents

-

-

Nickel-catalyzed Heck reaction of cycloalkenes using aryl sulfonates and pivalates

Nickel-catalyzed Heck reaction of cycloalkenes delivers unusual conjugated arylated isomers. Nickel(0) catalysts ligated by chelating dialkylphosphines effectively activate not only aryl triflates as electrophiles, but also less reactive aryl mesylates, t

Electro-Olefination—A Catalyst Free Stereoconvergent Strategy for the Functionalization of Alkenes

Conventional methods carrying out C(sp2)?C(sp2) bond formations are typically mediated by transition-metal-based catalysts. Herein, we conceptualize a complementary avenue to access such bonds by exploiting the potential of electrochemistry in combination with organoboron chemistry. We demonstrate a transition metal catalyst-free electrocoupling between (hetero)aryls and alkenes through readily available alkenyl-tri(hetero)aryl borate salts (ATBs) in a stereoconvergent fashion. This unprecedented transformation was investigated theoretically and experimentally and led to a library of functionalized alkenes. The concept was then carried further and applied to the synthesis of the natural product pinosylvin and the derivatization of the steroidal dehydroepiandrosterone (DHEA) scaffold.