109481-92-7Relevant academic research and scientific papers
Substituent Effect on the Chemical Behaviour of some Carbonyl Compounds and Ketals with 1-Ethoxy-3-Trimethylsilyl-prop-1-yne
Zakarya, D.,Rayadh, A.,Samih, M.,Lakhlifi, T.
, p. 405 - 408 (1994)
In this work, principal component analysis (PCA) was carried out on the basis of property descriptors for a set of carbonyl compounds and ketals.A principal component projection of the points representing the compounds showed that the chemical behaviour of the compounds with 1-ethoxy-3-trimethylsilylprop-1-yne is related to their chemical composition.The obtained structure-chemical behaviour information was used to design a space transition state of the studied reactions.
REACTION DE CYCLOADDITION ENTRE L'ETHOXY-1 TRIMETHYLSILYL-3 PROPYNE-1 ET LES ACETALS : SYNTHESE DE CARBETHOXY-2 TRIMETHYLSILANES ALLYLIQUES, DIENIQUES OU ENYNIQUES DIVERSEMENT SUBSTITUES
Pornet, J.,Rayadh, A.,Miginiac, L.
, p. 5479 - 5482 (2007/10/02)
In the presence of titanium tetrachloride, 1-ethoxy-3-trimethylsilyl-1-propyne easily reacts with many saturated, unsaturated or functional acetals to lead to 2-carbethoxy allylic, dienic or enynic trimethylsilanes, in a regioselective and often stereoselective way.
