1095062-41-1

Basic information

• Product Name: [RhCl(Ph₃P)2]
• CAS NO: 1095062-41-1
• Molecular Weight: 662.94
• Mol File: 1095062-41-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: [RhCl(Ph₃P)2](CAS DataBase Reference)
• NIST Chemistry Reference: [RhCl(Ph₃P)2](1095062-41-1)
• EPA Substance Registry System: [RhCl(Ph₃P)2](1095062-41-1)

Safety Data

• Hazardous Substances Data: 1095062-41-1(Hazardous Substances Data)

Upstream product

• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 
• 15318-33-9 trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I) 
• 14694-95-2 Wilkinson's catalyst 

Downstream Products

• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 
• 14653-50-0 [rhodium(I)chloride(triphenylphosphine)2]1 
• 142233-40-7 {1-tert-butyl-2-methyl-3-(2-propen-1-yl)-η5-1H-1,2-azaborolyl}-bis(triphenylphosphine)rhodium 

Relevant articles and documents

RhCl(CO)(PPh3)2.

Exclusive evolution of hydrogen without carbon monoxide was observed for the liquid-phase dehydrogenation of 2-propanol with trans- left bracket RhCl(CO)(PPh//3)//2 right bracket under MLCT irradiation, suggesting the catalytic role of the photogenerated left bracket RhCl(PPh//3)//2 right bracket species before its rapid replenishment with CO ligand. A quantum efficiency exceeding unity (1. 6) was obtained at 364 nm and 108 degree C in refluxing solution mixed with diglyme. Homogeneous photocatalysis in the visible region was discussed from the standpoint of energy storing.

Alkene and dihydrogen formation by catalytic dehydrogenation of alkane with RhCl(PR3)2 photo-generated from RhCl(CO)(PR3)2

Alkene and dihydrogen formation by photocatalytic dehydrogenation of alkanes using RhC1(CO)(PR3)2 proceeded with high turnover frequencies, amounting to 1404 h-1 for nonane at nonane at 135 ΔRG (PR3 = PMe3