14653-50-0

Basic information

• Product Name: {RhCl(PPh₃)₂}₂
• Synonyms: {RhCl(PPh₃)₂}₂
• CAS NO: 14653-50-0
• Molecular Weight: 1325.88
• Mol File: 14653-50-0.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: {RhCl(PPh₃)₂}₂(CAS DataBase Reference)
• NIST Chemistry Reference: {RhCl(PPh₃)₂}₂(14653-50-0)
• EPA Substance Registry System: {RhCl(PPh₃)₂}₂(14653-50-0)

Safety Data

• Hazardous Substances Data: 14653-50-0(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 69547-87-1 [RhHCl(2-benzylideneamino-3-methylpyridine^(1-))(PPh₃)2] 
• 603-35-0 triphenylphosphine 
• 89437-71-8 [exo-nido-(PPh3)2Rh(7,8-μ-(CH2)3-7,8-C2B9H10)]*benzene 
• 75-57-0 tetramethlyammonium chloride 
• 14694-95-2 tris(triphenylphosphine)rhodium(l) chloride 
• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 
• 1562376-74-2 trans-[rhodium(I)chloride(triphenylphosphine)2(phenylacetyl-(3,3′,5,5′-tetra-tert-butyl-1,1′-biphenyl-2,2′-diyl)phosphite)] 
• 1562376-73-1 trans-[rhodium(I)chloride(triphenylphosphine)2(phenylacetyl-(5,5′,6,6′-tetramethyl-3,3′-di-tert-butyl-1,1′-biphenyl-2,2′-diyl)phosphite)] 
• 1562376-72-0 trans-[rhodium(I)chloride(triphenylphosphine)2(propanoyl-(3,3′,5,5′-tetra-tert-butyl-1,1′-biphenyl-2,2′-diyl)phosphite)] 
• 1562376-71-9 trans-[rhodium(I)chloride(triphenylphosphine)2(propanoyl-(5,5′,6,6′-tetramethyl-3,3′-di-tertbutyl-1,1′-biphenyl-2,2′-diyl)phosphite)] 
• 14694-95-2 Wilkinson's catalyst 
• 41823-72-7 bis[bis(trimethylsilyl)methyl]tin(II) 
• 637-69-4 4-Methoxystyrene 

Downstream Products

• 15318-33-9 trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I) 
• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 
• 201733-38-2 [RhCl(BO₂C₆H₄)2(P(CH₃)2(C₆H₅))3] 
• 201733-51-9 [RhCl(BS₂C₆H₄)2(P(C₆H₅)3)2] 
• 144436-50-0 [(Ph₃P)2RhCl(phenylene-1,2-dioxyboryl)2] 
• 824426-56-4 [(Ph3P)2Rh(η6-C6H5Me)](ClB(C6F5)3) 
• 944942-36-3 [bis(triphenyphosphino)rhodium(benzene)][B(C₆H₃(CF₃)2-3,5)4] 
• 1346157-45-6 cis-RhCl(PPh₃)2(Et₂NH) 
• 112837-81-7 RhCl₃(P(C₆H₅)3)2(NHNC₆H₄OCH₃) 
• 112793-51-8 trans-chlorobis(triphenylphosphine)((p-methoxyphenyl)diazenido)rhodium tetrafluoroborate 
• 112793-54-1 (RhCl(P(C₆H₅)3)3(N₂C₆H₄OCH₃))⁽¹⁺⁾*BF₄^(1-)=(RhCl(P(C₆H₅)3)3(N₂C₆H₄OCH₃))BF₄ 
• 36581-28-9 RhCl₂(P(C₆H₅)3)2N₂C₆H₄OCH₃ 
• 112817-43-3 (RhCl₂(P(C₆H₅)3)2(NHNC₆H₄OCH₃))⁽¹⁺⁾*BF₄^(1-)=(RhCl₂(P(C₆H₅)3)2(NHNC₆H₄OCH₃))BF₄ 

Relevant articles and documents

Convenient synthesis and molecular structure of the cyclometallated complex [IrCl(H)(C6H4PPh2)(PPh3)2]

Dedicated to Professor Hubert Schmidbaur on the occasion of his 80th birthday The reaction of [{Ir(μ-Cl)(coe)2}2] (coe=cis-cyclooctene) with triphenylphosphane (molar ratio of Ir to P=1 : 3) in dichloromethane at room temperature afforded after a short reaction time the cyclometallated complex [IrCl(H)(C6H4PPh2)(PPh3)2] (1) in almost quantitative yield. The molecular structure of the title compound 1 was determined by an X-ray diffraction study.

Mixed anhydride complexes of rhodium(i) and ruthenium(ii)-their synthesis and ligand rearrangements

The coordination chemistry and solution behaviour of Rh(i) and Ru(ii) complexes derived from mixed anhydride ligands of carboxylic acids and phosphorus acids were explored. Similar to the free ligand systems, mixed anhydride complexes rearranged in solution via a number of pathways, with the pathway of choice dependent on the mixed anhydride employed, the auxiliary ligands present as well as the nature of the metal centre. Plausible mechanisms for some of the routes of rearrangement and by-product formation are proposed. Where stability allowed, new complexes were fully characterised, including solid state structures for four of the unrearranged mixed anhydride complexes and two of the interesting rearrangement products.

Rhodium-catalyzed intermodular hydroiminoacylation of alkenes: Comparison of neutral and cationic catalytic systems

Both cationic and neutral rhodium catalytic systems for the hydroiminoacylation of alkenes were studied using NMR spectroscopy and DFT-based methods. With neutral systems, the oxidative addition step was shown to be thermodynamically favored. With the cat