1095272-41-5Relevant academic research and scientific papers
Ni(0)-catalyzed conjugate addition of Me3SiCN to Ynones: α-bromo-β-cyano tetrasubstituted enones
Arai, Takayoshi,Suemitsu, Yuuki,Ikematsu, Yui
supporting information; experimental part, p. 333 - 335 (2009/07/04)
(Chemical Equation Presented) Conjugate addition of Me3SiCN to ynones is smoothly catalyzed by Ni(cod)2 to give the β-cyanosilyloxyallene quantitatively. Further reaction of the silyloxyallenes with NBS provides the tetrasubstituted
