1095280-73-1

Basic information

• Product Name: N-Boc-N-(3-methylphenyl)-O-(4-nitrobenzoyl)hydroxylamine
• Synonyms: N-Boc-N-(3-methylphenyl)-O-(4-nitrobenzoyl)hydroxylamine
• CAS NO: 1095280-73-1
• Molecular Weight: 372.378
• Mol File: 1095280-73-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Boc-N-(3-methylphenyl)-O-(4-nitrobenzoyl)hydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Boc-N-(3-methylphenyl)-O-(4-nitrobenzoyl)hydroxylamine(1095280-73-1)
• EPA Substance Registry System: N-Boc-N-(3-methylphenyl)-O-(4-nitrobenzoyl)hydroxylamine(1095280-73-1)

Safety Data

• Hazardous Substances Data: 1095280-73-1(Hazardous Substances Data)

Upstream product

• 1095280-69-5 N-Boc-N-(3-methylphenyl)hydroxylamine 
• 122-04-3 4-nitro-benzoyl chloride 

Downstream Products

• 191112-67-1 (2-hydroxy-5-methylphenyl)carbamic acid tert-butyl ester 
• 440359-60-4 3-t-butyloxycarbonylamino-2-hydroxytoluene 

Relevant articles and documents

Rearrangement of differentially protected N-arylhydroxylamines

The rearrangement of a series of N,O-difunctionalised N-arylhydroxylamines to generate protected 2-aminophenols has been investigated. N-Boc-N-Aryl-O- acylhydroxylamines are stable, isolable compounds which rearrange smoothly at temperatures between 110 and 140°C. The corresponding N-Boc-N-aryl-O- sulfonylhydroxylamines were not isolated and rearrange to 1,2-difunctionalised aminophenols at room temperature in excellent yield. Deprotection of either the N- or O-substituents under standard conditions allows for further synthetic manipulation of either the aniline or phenol functionality. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.