1095393-70-6Relevant articles and documents
Kinetic resolution of primary amines via enantioselective N-acylation with acyl chlorides in the presence of supramolecular cyclodextrin nanocapsules
Asahara, Haruyasu,Kida, Toshiyuki,Iwamoto, Takuya,Hinoue, Tomoaki,Akashi, Mitsuru
, p. 197 - 203 (2014/01/06)
The non-enzymatic kinetic resolution of primary amines via enantioselective N-acylation with acyl chlorides was accomplished for the first time by using the selective sequestration of one enantiomer within a supramolecular cyclodextrin (CD) nanocapsule in nonpolar solvents. In addition, the first example of a crystalline structure for an inclusion complex between an acyl chloride and a CD derivative is reported.