109574-79-0Relevant articles and documents
SYNTHESIS OF OPTICALLY ACTIVE 4-HYDROXYALK-2-ENENITRILES; REACTION OF OPTICALLY ACTIVE 2-(p-CHLOROPHENYLSULFINYL)ACETONITRILE WITH ALDEHYDES IN THE PRESENCE OF PIPERIDINE IN ACETONITRILE
Nokami, Junzo,Mandai, Tadakatsu,Nishimura, Akira,Takeda, Takashi,Wakabayashi, Shoji,et al.
, p. 5109 - 5112 (2007/10/02)
Reaction of optically active 2-(p-chlorophenylsulfinyl)acetonitrile ((R)-1a) with aldehydes, in the presence of piperidine in acetonitrile at r.t., gave optically active 4-hydroxyalk-2-enenitriles in good optical and chemical yields.The absolute configura