109592-16-7Relevant academic research and scientific papers
Influence of structural features of tri-functionalized aryl phosphates on the outcome of the SRN1 process with stannyl anions: A DFT study
Dorn, Viviana B.,Silbestri, Gustavo F.,Lockhart, María T.,Chopa, Alicia B.,Pierini, Adriana B.
, p. 1150 - 1156 (2013/06/27)
Under irradiation, 1,3-bis(diethoxyphosphoryloxy)-4-chlorobenzene (2), 1,4-bis(diethoxyphosphoryloxy)-3-chlorobenzene (3) and 1,3- bis(diethoxyphosphoryloxy)-5-chlorobenzene (4) react with trimethyltinsodium (1) in liquid ammonia giving entirely different distribution of stannylated products. These differences are explained through theoretical DFT studies. Experimental evidence for the involvement of an SRN1 mechanism was obtained.
PHOSPHORYLATED OCTAHYDROXY4>METACYCLOPHANES
Kal'chenko, V.I.,Rudkievich, D.M.,Shivanyuk, A.N.,Tsymbal, I.F.,Pirozhenko, V.V.,Markovskii, L.N.
, p. 663 - 672 (2007/10/02)
Cyclophanes functionalized at the periphery of the macrocyle by four or eight phosphoryl groups are synthesized by phosphorylation of octahydroxy4>metacyclophanes with phosphorus(V) acid chlorides or with the system dialkyl hydrogen phosphite
