1096001-27-2Relevant articles and documents
Practical one-pot, three-component synthesis of N-heterocyclic carbene (NHC) ligated palladacycles derived from n,n-dimethylbenzylamine
Kantchev, Eric Assen B.,Ying, Jackie Y.
, p. 289 - 299 (2009)
Further explorations of the catalytic potential of N-heterocyclic carbene (NHC) ligated palladacycles as catalysts for Pd-mediated transformations have been hampered by the lack of general and practical methods for their synthesis. In this work, we descri
Dioxygen activation with stable N-heterocyclic carbenes
Tang, Jinghua,Gao, Xuejiao J.,Tang, Huarong,Zeng, Xiaoming
supporting information, p. 1584 - 1587 (2019/02/07)
Dioxygen activation with both cyclic (amino)(alkyl)carbenes and di(amino)carbenes at ambient temperature is described. Theoretical studies suggest that electron rearrangement from the doubly filled σ orbital of carbene carbon to its vacant p orbital through the π? antibonding orbital of 3O2 can be considered for Ccarbene-O bond formation.
Dual reactivity of N-heterocyclic carbenes towards copper(ii) salts
Kolychev, Eugene L.,Shuntikov, Viacheslav V.,Khrustalev, Victor N.,Bush, Alexander A.,Nechaev, Mikhail S.
body text, p. 3074 - 3076 (2011/05/14)
Complexes of N-heterocyclic carbenes (NHCs) with copper(ii) halogenides are unstable. Upon formation, these complexes decompose to give haloamidinium salts. Contrastingly, O-substituted copper(ii) NHC complexes are fairly stable. A series of new five-, si