109681-47-2Relevant academic research and scientific papers
THE SILAPINACOL REARRANGEMENT: CONVERSION OF α,β-DIHYDROXYSILANES INTO α-SILYL CARBONYL COMPOUNDS
Cunico, Robert F.
, p. 4269 - 4272 (1986)
Treatment of α,β-dihydroxysilanes with trifluoroacetic acid in chloroform results in a 1,2-migration of the silyl group to give α-silyl aldehydes and ketones.The t-butyl-dimethylsilyl compounds can be isolated in high yields.
