Tetrahedron Letters p. 4269 - 4272 (1986)
Update date:2022-08-03
Topics:
Cunico, Robert F.
Treatment of α,β-dihydroxysilanes with trifluoroacetic acid in chloroform results in a 1,2-migration of the silyl group to give α-silyl aldehydes and ketones.The t-butyl-dimethylsilyl compounds can be isolated in high yields.
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(1960)
