1097200-09-3Relevant academic research and scientific papers
Transition-metal-free arylations via photogenerated triplet 4-alkyl- and 4-trimethylsilylphenyl cations
Qrareya, Hisham,Raviola, Carlotta,Protti, Stefano,Fagnoni, Maurizio,Albini, Angelo
, p. 6016 - 6024 (2013/07/26)
The irradiation in protic solvents of 4-chloroalkylbenzenes and 4-chlorophenyltrimethylsilane caused the heterolytic cleavage of aryl-chlorine bonds to give the corresponding triplet phenyl cations. These were exploited for transition-metal-free arylation reactions under mild conditions to give allylbenzenes, γ-benzyl lactones, 3-arylacetals (ketals), and biaryls in moderate to good yields. The path followed was supported by DFT calculations at the UB3LYP/6-311+G(2d,p) level.
Photoinduced three-component reaction: A convenient access to 3-arylacetals or 3-arylketals
Lazzaroni, Simone,Protti, Stefano,Fagnoni, Maurizio,Albini, Angelo
supporting information; experimental part, p. 349 - 352 (2009/08/15)
(Chemical Equation Presented) A mild and versatile method for the photoinduced three-component synthesis of 3-arylacetals and ketals is presented. Desired targets are smoothly obtained by irradiating aromatic halides or esters in alcohols, in the presence
