109771-12-2Relevant articles and documents
Total regioselective control of tartaric acid
Spengler, Jan,Fernandez-Llamazares, Ana I.,Ruiz-Rodriguez, Javier,Burger, Klaus,Albericio, Fernando
supporting information; scheme or table, p. 5746 - 5749 (2010/10/20)
An efficient strategy to synthesize tartaric acid building blocks for totally regioselective transformations or derivatizations was disclosed. Starting from l-tartaric acid or l-dimethyl tartrate, respectively, we obtained type I and II building blocks with orthogonal sets of protecing groups (4-8 steps, 38-56% overall yield).
Selective monoalkylation of acyclic diols by means of dibutyltin oxide and fluoride salts
Nagashima,Ohno
, p. 1972 - 1982 (2007/10/02)
Fluoride anion was found to promote monoalkylation reaction of diols by the stannylene acetal method, and selective monoalkylation of various acyclic diols was accomplished in good yields under mild conditions by employing this new method. Functional groups such as carboxylic acid ester, carboxamide, carbamate, nitrile, alkyl chloride, and ether were not affected under the reaction conditions.
An Efficient O-Monoalkylation of Dimethyl L-Tartrate via O-Stannylene Acetal with Alkyl Halides in the Presence of Cesium Fluoride
Nagashima, Nobuo,Ohno, Masaji
, p. 141 - 144 (2007/10/02)
Selective O-monoalkylation of the vic-glycol of dimethyl L-tartrate with alkyl halides has been found to take place smoothly under mild conditions in the presence of cesium fluoride.