1097939-38-2Relevant academic research and scientific papers
Palladium-catalyzed cross-coupling reactions of organogold(i) phosphanes with allylic electrophiles
Pena-Lopez, Miguel,Ayan-Varela, Miguel,Sarandeses, Luis A.,Sestelo, Jose Perez
experimental part, p. 1686 - 1694 (2012/03/22)
Aryl and alkenylgold(i) phosphanes react regioselectively with allylic electrophiles such as cinnamyl and geranyl halides (bromide, chloride and acetates) under palladium catalysis in THF at 80 °C to afford the α-substitution product with moderate to high yields. When the reaction is performed with a chiral enantiopure secondary acetate, the α-substituted cross-coupling product is obtained with complete inversion of the stereochemistry.
Iron-catalyzed 1,4-addition of α-olefins to dienes
Moreau, Benoit,Wu, Jessica Y.,Ritter, Tobias
supporting information; experimental part, p. 337 - 339 (2009/07/04)
Stereo-and Regiosetective 1,4-Addition A new intermolecular, stereo- and regioselective iron-catalyzed 1,4-addition of α-olefins to 1,3-dlenes using as low as 1 mol % of an iminopyridine-ferrous chloride complex was developed. Importantly, both double bon
