109802-94-0

Basic information

• Product Name: cis-1-cyano-5-carbomethoxy-6-methylcyclohexene
• Synonyms: cis-1-cyano-5-carbomethoxy-6-methylcyclohexene
• CAS NO: 109802-94-0
• Molecular Weight: 179.219
• Mol File: 109802-94-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-1-cyano-5-carbomethoxy-6-methylcyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: cis-1-cyano-5-carbomethoxy-6-methylcyclohexene(109802-94-0)
• EPA Substance Registry System: cis-1-cyano-5-carbomethoxy-6-methylcyclohexene(109802-94-0)

Safety Data

• Hazardous Substances Data: 109802-94-0(Hazardous Substances Data)

Upstream product

• 102860-19-5 (E)-2-(phenylsulfonyl)-1,3-pentadiene 
• 102815-50-9 5-(chloromercuri)-4-(phenylsulfonyl)pent-2-ene 
• 151-50-8 potassium cyanide 
• 109862-70-6 cis-4-carbomethoxy-3-methyl-1-(phenylsulfonyl)cyclohexene 

Relevant articles and documents

The use of metal reagents in stereo- and regioselective functionalizations of conjugated dienes

Conjugated dienes have been selectively functionalized via 1-acetoxy-4-chloro-2-alkenes and via 2-(phenylsulfonyl)-1,3-dienes.In both these approaches nucleophiles can be added to the 1- and 4-positions.It was shown that also non-stabilized carbon nucleophiles (from cuprates or copper(I)-catalyzed Grignard reactions) can be used.The utility of the functionalizations was demonstrated by the syntheses of a marine natural product and a butterfly pheromone.Finally, the 2-(phenyl-sulfonyl)-1,3-dienes show a dual electron demand in Diels-Alder reactions and give cycloadducts with both electron-rich and electron-deficient olefins.