109821-39-8Relevant articles and documents
α-Alkylation of Ketones with Alkenes Enabled by Photoinduced Activation of Silyl Enol Ethers in the Presence of a Small Amount of Water
Hirata, Tsubasa,Ogasawara, Yoshihiro,Yamashita, Yasuhiro,Kobayashi, Shū
, p. 5693 - 5697 (2021)
Under blue-light irradiation conditions with a photocatalyst [1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene], silyl enol ethers reacted with alkenes in the presence of a small amount of water to afford the α-alkylation products in good to high yields. A thiol cocatalyst was found to expand the substrate scope of the reaction.