109906-52-7

Upstream product

• 76644-52-5 rac-3-acetoxycyclohexene 

Downstream Products

• 3298-40-6 mesoxalate de methyle 
• 76644-52-5 rac-3-acetoxycyclohexene 
• 92838-30-7 Acetic acid (1S,2R,3S)-3-isocyano-2-trimethylsilanyloxy-cyclohexyl ester 
• 92838-29-4 (1R,2S,3R)-3-Isocyano-cyclohexane-1,2-diol 
• 143218-39-7 (1R^*,2S^*,6R^*)-2-acetoxy-6-butylcyclohexanol 
• 143218-40-0 (1R^*,2S^*,3R^*)-2-acetoxy-3-butylcyclohexanol 
• 143218-39-7 (1R^*,2R^*,6S^*)-2-acetoxy-6-butylcyclohexanol 
• 143218-40-0 (1R^*,2R^*,3S^*)-2-acetoxy-3-butylcyclohexanol 

Relevant academic research and scientific papers

SYN-STEREOSELECTIVE EPOXIDATION OF ALLYLIC ETHERS USING CF3CO3H

Good syn-stereoselectivity is observed in the epoxidation of allylic ethers with CF3CO3H, indicating a new type of hydrogen-bonded transition state.

1-ACETOXY-2-CYCLOHEXENE OXIDATION IN THE PRESENCE OF MOLYBDENUM, VANADIUM AND CHROMIUM COMPOUNDS

A study has been made on the catalytic oxidation of ACH-2 with molecular oxygen.The composition of reaction products (1-acetoxy-2-cyclohexene-4-one, 1-acetoxy-2-cyclohexene-4-ol) and their formation pathway have been analyzed.In MoO2(acac)2 catalysis, 1-acetoxy-2,3-epoxycyclohexane is formed. In an ACH-2 medium, the catalytic HP-decomposition mechanism and reaction yields have been investigated.The HP-decomposition have been shown to proceed through intermediate complexes over catalysts with the following overall decomposition rate constants: The hydroperoxide decomposes mainly heterolytically in the presence of MoO2(acac)2.With Cr(acac)2 the radical decomposition fraction amounts to under 1percent.