92838-29-4

Upstream product

• 92838-30-7 Acetic acid (1S,2R,3S)-3-isocyano-2-trimethylsilanyloxy-cyclohexyl ester 
• 60464-75-7 <(cis-2,3-epoxycyclohexan-1-yl)oxy>trimethylsilane 
• 26819-57-8 cis-1-acetoxy-2,3-epoxycyclohexan 
• 60464-75-7 <(trans-2,3-epoxycyclohexan-1-yl)oxy>trimethylsilane 
• 92838-28-3 (1S,2R,3R)-1-Isocyano-2,3-bis-trimethylsilanyloxy-cyclohexane 
• 92838-28-3 (1S,2R,3S)-1-Isocyano-2,3-bis-trimethylsilanyloxy-cyclohexane 

Downstream Products

• 92936-36-2 (1R,2R,3S)-3-Amino-cyclohexane-1,2-diol; hydrochloride 
• 92936-36-2 (1RS,2SR,3RS)-3-aminocyclohexane-1,2-diol hydrochloride 

Relevant academic research and scientific papers

DIRECTIVE EFFECTS IN THE OPENING OF EPOXIDES WITH TRIMETHYLSILYL CYANIDE- ZINC IODIDE. THE ESTABLISHMENT OF THREE CONTIGUOUS CHIRAL CENTERS.

Adjacent hydroxyl, trimethylsiloxyl, and acetoxyl groups have been shown to provide complete control over the regiospecifity of the opening of epoxides by trimethylsilyl cyanide - zinc iodide.Thus, cyclohex-2-en-R-1-ol can be readily converted into (1R,2S,3R)-3-aminocyclohexan-1,2-diol.