109918-91-4Relevant academic research and scientific papers
AUTOOXIDATION OF ACETYLENES AND THEIR DERIVATIVES. XXV. 1-PHENYL-4-PENTEN-1-YN-3-0L AND 1-PHENYL-4-HEXEN-1-YN-3-OL
Stepin, S. G.,Tishchenko, I. G.
, p. 1771 - 1774 (2007/10/02)
During the autooxidation of secondary enynyl alcohols attack by oxygen takes place at the C-H bonds at the α position to the triple and double bonds and the hydroxyl group.The initially formed unstable hydroxyhydroperoxides dissociate under the oxidation conditions into the corresponding enynyl ketones, acetylenic keto epoxydes, and products from degradation of the carbon skeleton.
