1099672-01-1 Usage
Description
4-Bromo-2-isopropoxybenzaldehyde is an organic compound characterized by the presence of a bromine atom at the 4-position, an isopropoxy group at the 2-position, and a benzaldehyde functional group. It is a versatile intermediate in organic synthesis, known for its unique structural features and reactivity.
Uses
Used in Pharmaceutical Industry:
4-Bromo-2-isopropoxybenzaldehyde is used as a reactant in the preparation of dihydrobenzopyrans, which are important scaffolds in the synthesis of various pharmaceutical compounds. The hydride transfer initiated cyclization of ortho-vinylaryl alkyl ethers allows for the efficient construction of these heterocyclic structures, which can be further modified for the development of new drugs with potential therapeutic applications.
Used in Organic Synthesis:
4-Bromo-2-isopropoxybenzaldehyde serves as a valuable building block in organic synthesis, particularly for the synthesis of complex organic molecules and natural products. Its unique structural features, such as the bromine atom and isopropoxy group, can be utilized in various synthetic transformations, enabling the formation of a wide range of target molecules with diverse applications in materials science, agrochemicals, and other fields.
Used in Chemical Research:
4-Bromo-2-isopropoxybenzaldehyde is also employed as a research tool in the study of reaction mechanisms, synthetic methodologies, and the development of new catalysts and reagents. Its reactivity and structural features make it an attractive candidate for exploring novel synthetic routes and understanding the underlying principles governing various chemical transformations.
Check Digit Verification of cas no
The CAS Registry Mumber 1099672-01-1 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,9,9,6,7 and 2 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1099672-01:
(9*1)+(8*0)+(7*9)+(6*9)+(5*6)+(4*7)+(3*2)+(2*0)+(1*1)=191
191 % 10 = 1
So 1099672-01-1 is a valid CAS Registry Number.
1099672-01-1Relevant articles and documents
Olefin Metathesis-Based Fluorescent Probes for the Selective Detection of Ethylene in Live Cells
Toussaint, Sacha N. W.,Calkins, Ryan T.,Lee, Sumin,Michel, Brian W.
, p. 13151 - 13155 (2018)
Ethylene is an important plant hormone that is involved in a variety of developmental processes including agriculturally important ripening of certain fruits. Owing to its significant roles, a number of approaches have previously been developed to detect ethylene via molecular interactions. However, there are no current approaches for detection that are selective via a discrete homogeneous molecular interaction. Here we report two profluorescent chemodosimeters for the selective detection of the plant hormone ethylene. The approach consists of a BODIPY fluorophore with a pendant ruthenium recognition element based on a Hoveyda-Grubbs second generation catalysts. A marked increase in fluorescence is observed upon exposure to ethylene and selectivity is observed for ethylene over other alkenes, providing a unique approach toward ethylene detection. Imaging in live cells demonstrated that ethylene could be detected from multiple relevant sources.
C-H bond functionalization via hydride transfer: synthesis of dihydrobenzopyrans from ortho-vinylaryl akyl ethers
McQuaid, Kevin M.,Long, Jonathan Z.,Sames, Dalibor
supporting information; experimental part, p. 2972 - 2975 (2009/12/05)
The hydride transfer initiated cyclization ("HT-cyclization") of aryl alkyl ethers, which leads to direct coupling of sp3 C-H bonds and activated alkenes, is reported. Readily available salicylaldehyde derived ethers are converted in one step to dihydrobenzopyrans, an important class of heteroarenes frequently found in biologically active compounds. This process has not been previously reported, in contrast to known HTcyclizations of the corresponding fert-amines ("tert-amino effect" reactions).
