110023-89-7Relevant academic research and scientific papers
A STEREOSELECTIVE SYNTHESIS OF THE AZASPIROUNDECANE RING SYSTEM OF (-)-HISTRIONICOTOXIN FROM (+)-GLUTAMIC ACID.
Winkler, Jeffrey D.,Hershberger, Paul M.,Springer, James P.
, p. 5177 - 5180 (2007/10/02)
We describe herein the first stereoselective synthesis of the natural (-)-histrionicotoxin ring system, where the chirality is derived from L-glutamic acid.The key transformation involves intramolecular dioxolenone photocycloaddition of a substrate derive
