1100829-95-5Relevant academic research and scientific papers
Stable 5-substituted cyclopentadienes for the Diels-Alder cycloaddition and their application to the synthesis of palau'amine
Hudon, Jonathan,Cernak, Timothy A.,Ashenhurst, James A.,Gleason, James L.
, p. 8885 - 8888 (2008)
(Chemical Equation Presented) Putting the brakes on a hydride shift: The incorporation of a 2-silyloxy group increases both the stability and reactivity of 5-substituted cyclopentadienes, thus facilitating their preparation and use (see scheme; Bz=benzyl, TBS=tert-butyldimethylsilyl). This approach has been applied to the synthesis of the E ring in the marine alkaloid palau'amine.
