110091-16-2Relevant academic research and scientific papers
DARSTELLUNG CYCLOMETALLIERTER, HALOGENVERBRUECKTER ZWEIKERNKOMPLEXE DES PALLADIUMS UND PLATINS
Abicht, Hans-Peter
, p. 57 - 62 (1986)
A new synthesis has been described for the monometallated binuclear complexes of the type (M=Pd, Pt; E=P, As).The halogenbridged binuclear palladium and platinum complexes are readily obtained by the oxidative addition of o-bromobenzyldiorgano-phosphines and -arsines, respectively to M(dba)2 (dba=dibenzylideneacetone).The resulting compounds are characterized by NMR spectroscopic data.The reactions with PPh3 and o-LiC6H4CH2PPh2 have been discussed.
