1101183-61-2Relevant academic research and scientific papers
Reactions of ortho-lithiophenyl (-hetaryl) isocyanides with carbonyl compounds: Rearrangements of 2-metalated 4H-3,1-benzoxazines
Lygin, Alexander V.,De Meijere, Armin
, p. 4554 - 4559 (2009)
(Chemical Equation Presented) ortho-Lithiophenyl (-hetaryl) isocyanides react with aldehydes and ketones providing isocyanoalcohols 8 (36-89%, nine examples), 4H-3,1-benzoxazines 9 (45-78%, six examples) or, after two types of rearrangements, isobenzofura
ortho-Lithiophenyl isocyanide: A versatile precursor for 3H-quinazolin-4-ones and 3H-quinazolin-4-thiones
Lygin, Alexander V.,De Meijere, Armin
supporting information; experimental part, p. 389 - 392 (2009/09/05)
(Chemical Equation Presented) ortho-Lithiophenyl isocyanide has been generated from ortho-bromophenyl isocyanide and successfully employed toward the synthesis of 2-substituted phenyl Isocyanides as well as 2,3-disubstituted 3H-quinazoline-4-ones and 3H-q
