1101881-91-7

Basic information

• Product Name: 1-(2-bromo-3-methylphenyl)ethanol
• Synonyms: 1-(2-bromo-3-methylphenyl)ethanol
• CAS NO: 1101881-91-7
• Molecular Weight: 215.09
• Mol File: 1101881-91-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(2-bromo-3-methylphenyl)ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-bromo-3-methylphenyl)ethanol(1101881-91-7)
• EPA Substance Registry System: 1-(2-bromo-3-methylphenyl)ethanol(1101881-91-7)

Safety Data

• Hazardous Substances Data: 1101881-91-7(Hazardous Substances Data)

Upstream product

• 109179-31-9 2-bromo-3-methyl-benzaldehyde 
• 676-58-4 methylmagnesium chloride 

Downstream Products

• 1101882-03-4 1-(2-bromo-3-methylphenyl)ethyl 2-methoxynaphthalene-1-sulfonate 

Relevant articles and documents

Atroposelective radical aryl migration reactions from sulfur to carbon

The paper describes stereoselective radical aryl migration reactions from sulfur in sulfonates to aryl radicals for the synthesis of axially chiral biaryls. A chirality center in secondary benzylic sulfonates is used to diastereoselectively (atroposelectively) install a stereogenic axis via a 1,5 aryl migration reaction. Atroposelectivity has not been investigated in stereoselective radical chemistry before. Good yields (53-82%) but low selectivities (up to 2 to 1) were obtained.