110195-07-8Relevant academic research and scientific papers
Yttrium compounds: New catalysts for the regioselective acylative cleavage of epoxides
Qian,Zhu
, p. 2203 - 2214 (1994)
The use of Cp2YCl and YCl3 as effective catalysts for the regioselective acylative cleavage of epoxides, especially for the conversion of α,β- epoxyketones to α-chloroenones is described.
Remarkable dependency of the regioselectivity in the ring opening of α,β-epoxyketones upon tin halide-Lewis base complexes as catalysts
Shibata,Yoshimura,Baba,Matsuda
, p. 7149 - 7152 (2007/10/02)
Tin halide-base complexes are used as catalysts for controlling the regioselectivity in the reaction of α,β-epoxyketones with electrophiles. Bu2SnX2-Ph3P complex caused the cleavage of the C-O bond adjacent to the carbonyl
