110205-68-0Relevant academic research and scientific papers
Synthesis and biological evaluation of the first example of an eight-membered iminoalditol
Godin, Guillaume,Garnier, Elodie,Compain, Philippe,Martin, Olivier R.,Ikeda, Kyoko,Asano, Naoki
, p. 579 - 581 (2004)
The synthesis of the first examples of eight-membered iminoalditols has been achieved from 2,3,4,6-tetra-O-benzyl-D-glucopyranose by way of a ring-closing metathesis. The (2R,3R,4R,5S)-2-hydroxymethyl-azocane-3,4,5-triol (3a), which has the D-gluco config
First total synthesis of (+)-hyacinthacine A2
Rambaud, Lauriane,Compain, Philippe,Martin, Olivier R.
, p. 1807 - 1809 (2001)
The first synthesis of (+)-hyacinthacine A2 has been achieved in six steps from 2,3,5-tri-O-benzyl-D-arabinofuranose in an overall yield of 11%. The structure of this natural product was thus unambiguously established as (1R,2R,3R,7aR)-1,2-dihydroxy-3-hydroxymethylpyrrolizidine
Intramolecular ketonitrone-olefin cycloaddition reaction: direct and stereocontrolled synthesis of nitrogenated quaternary centered aminocyclopentitols as galactosidase inhibitors
Suman Reddy,Kadigachalam,Doddi, Venkata Ramana,Vankar, Yashwant D.
scheme or table, p. 5827 - 5830 (2010/01/11)
Synthesis of nitrogenated quaternary centered polyhydroxylated aminocyclopentanes by implementation of ketonitrone-olefin cycloaddition reaction as a key step has been accomplished in a stereocontrolled manner. The target molecules were found to be modera
Stereospecific synthesis of eight-membered polyhydroxy carbocycles via TIBAL-promoted claisen rearrangement
Han, Tianxiang,Liu, Yi,Yang, Zhenjun,Zhang, Liangren,Zhang, Lihe
supporting information; scheme or table, p. 1985 - 1988 (2009/04/07)
The stereoselective synthesis of novel eight-membered polyhydroxy carbocycles was achieved from D-glucose via mercuriocyclization and triisobutylaluminum (TIBAL)-promoted Claisen rearrangement. Along with rearrangement, TIBAL also promoted debenzylation a
An efficient synthetic approach to aza-C-glycosyl compounds. Application to the synthesis of an aza-C-disaccharide
Martin, Olivier R.,Liu, Li,Yang, Feng
, p. 1991 - 1994 (2007/10/03)
The NIS-mediated cyclization of aminoheptenitols 5-8 (prepared in three steps from tetra-O-benzyl-D-hexopyranoses) provided 1,2,6-trideoxy-2,6-imino-l-iodoheptitol derivatives 9-12, respectively, highly stereoselectively and in high yield. The "α-D-glucoα
