79258-18-7

Upstream product

• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 19493-09-5 Methylenetriphenylphosphorane 
• 100-44-7 benzyl chloride 
• 93125-77-0 (2R,3R,4R,5S)-1,3,4-tris(benzyloxy)hept-6-ene-2,5-diol 
• 1193390-71-4 (2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-2-(benzyloxymethyl)-6-(bis(phenylsulfonyl)methyl)tetrahydro-2H-pyran 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 162239-07-8 1-deoxy-1-α-ethenyl-2,3,5-tri-O-benzyl-L-xylose 
• 182265-87-8 (2R,3S,4R,5R,6R)-3,4,5,7-Tetrakis-benzyloxy-heptane-1,2,6-triol 
• 182124-65-8 3,4,5,7-tetra-O-benzyl-D-glycero-D-gulitol 
• 162239-11-4 (2S,3R,4R,5S)-1,3,4,5-Tetrakis-benzyloxy-hept-6-en-2-ol 
• 592496-96-3 C₃₇H₄₀O₅ 
• 669015-46-7 Allyl-((2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-hex-5-enyl)-amine 
• 669015-47-8 Allyl-((2R,3R,4S)-2,3,4-tris-benzyloxy-1-benzyloxymethyl-hex-5-enyl)-carbamic acid benzyl ester 
• 129173-16-6 3,6-anhydro-4,5,7-tri-O-benzyl-1,2-dideoxy-D-manno-hept-1-enitol 
• 1092502-86-7 (2ξ)-1,2-anhydro-3,4,5,7-tetra-O-benzyl-D-gluco-heptitol 
• 165878-71-7 C₃₅H₃₇IO₅ 
• 1262890-10-7 2,3,4,5,7-penta-O-benzyl-6-O-triethylsilyl-D-glycero-D-gulose 
• 1262890-09-4 2,3,4,5,7-penta-O-benzyl-1,6-bis-O-triethylsilyl-D-glycero-D-gulitol 
• 1262890-08-3 2,3,4,5,7-penta-O-benzyl-D-glycero-D-gulitol 
• 1262890-07-2 3,4,5,7-tetra-O-benzyl-1,2-O-benzylidene-D-glycero-D-gulitol 

Relevant academic research and scientific papers

A Mitsunobu route to C-glycosides

C-Glycosides were successfully prepared via dehydrative alkylation under Mitsunobu conditions, using substituted sulfonyl methanes as nucleophiles. The materials prepared were converted to useful C-glycoside intermediates. An application of this approach

Intramolecular ketonitrone-olefin cycloaddition reaction: direct and stereocontrolled synthesis of nitrogenated quaternary centered aminocyclopentitols as galactosidase inhibitors

Synthesis of nitrogenated quaternary centered polyhydroxylated aminocyclopentanes by implementation of ketonitrone-olefin cycloaddition reaction as a key step has been accomplished in a stereocontrolled manner. The target molecules were found to be modera

Enzyme-catalyzed synthesis of isosteric phosphono-analogues of sugar nucleotides

Efficient enzymatic syntheses of isosteric phosphono analogues of sugar nucleotides have been accomplished using a thymidylyltransferase. The Royal Society of Chemistry.

Stereoselective synthesis of branched cyclopentitols by titanium(III)-promoted reductive cyclization of 4-oxiranylaldehydes and 4-oxiranyl ketones derived from hexoses

Titanocene chloride efficiently promotes the intramolecular reductive cross coupling of highly functionalized 4-oxiranyl-aldehydes and 4-oxiranyl ketones derived from readily available hexoses affording branched cyclopentitols with good stereoselectivity.

Stereospecific synthesis of eight-membered polyhydroxy carbocycles via TIBAL-promoted claisen rearrangement

The stereoselective synthesis of novel eight-membered polyhydroxy carbocycles was achieved from D-glucose via mercuriocyclization and triisobutylaluminum (TIBAL)-promoted Claisen rearrangement. Along with rearrangement, TIBAL also promoted debenzylation a

Synthesis and biological evaluation of the first example of an eight-membered iminoalditol

The synthesis of the first examples of eight-membered iminoalditols has been achieved from 2,3,4,6-tetra-O-benzyl-D-glucopyranose by way of a ring-closing metathesis. The (2R,3R,4R,5S)-2-hydroxymethyl-azocane-3,4,5-triol (3a), which has the D-gluco config

Carbohydrate-based oxepines: Ring expanded glycals for the synthesis of septanose saccharides

A ring-closing metathesis (RCM) approach to a family of carbohydrate-based oxepines is described. A variety of readily accessible, protected monosaccharide derived dienes were used to demonstrate the utility of the synthetic sequence and to investigate ho

First total synthesis of (+)-hyacinthacine A2

The first synthesis of (+)-hyacinthacine A2 has been achieved in six steps from 2,3,5-tri-O-benzyl-D-arabinofuranose in an overall yield of 11%. The structure of this natural product was thus unambiguously established as (1R,2R,3R,7aR)-1,2-dihydroxy-3-hydroxymethylpyrrolizidine

Spontaneous cyclization of triflates derived from δ-benzyloxy alcohols: Efficient and general synthesis of C-vinyl furanosides

On reaction with triflic anhydride, the hept-1-enitols resulting from the Wittig reaction of tetra-O-benzyl D-hexopyranoses with [Ph3P=CH2] lead, in one step, to 3,6-anhydro-hept-1-enitol derivatives ('C-vinyl furanosides') in high y