110211-43-3Relevant academic research and scientific papers
Cadmium chloride mediated regiocontrol of dienolates and ketene thioacetals: γ condensation with aldehydes
Lei, Bo,Fallis, Alex G.
, p. 1450 - 1456 (2007/10/02)
The use of cadmium chloride to control the regioselectivity of vinylogous anions upon condensation with aldehydes is described.Addition occurred preferentially at the γ position with substituted crotonates and 2-ethylidene-1,3-dithiane (6).Experiments dem
REGIOSELECTIVE CONTROL OF ALLYL ANIONS WITH CADMIUM CHLORIDE: α vs. γ CONDENSATION WITH ALDEHYDES
Bo, Lei,Fallis, Alex G.
, p. 5193 - 5196 (2007/10/02)
A general method for directing the condensation of allyl anions such as 2 with aldehydes preferentially to the γ position of the unsaturated nucleophile is described.The procedure employs cadmium chloride to control the regioselectivity and will facilitat
