110230-41-6Relevant academic research and scientific papers
Reaction of Trifluoromethyl Ketones. IV. Cyclization of the Ene Reaction Products of Trifluoromethyl Ketones: A Facile Synthesis of 2-(Trifluoromethyl)tetrahydrofuran
Nagai, Takabumi,Miki, Takuichi,Kumadaki, Itsumaro
, p. 3620 - 3627 (2007/10/02)
1-(Trifluoromethyl)homoallyl alcohols, which were obtained by the ene reaction of trifluoromethyl ketones with olefins, were cyclized to 2-(trifluoromethyl)tetrahydrofurans in the presence of p-toluenesulfonic acid, a typical Brensted acid.The ease of thi
Reaction of Trifluoromethyl Ketones. III. The Aluminium Chloride Assisted Ene Reaction of 1,1,1-Trifluoro-2-hexanone and α,α,α-Trifluoroacetophenone
Nagai, Takabumi,Miki, Takuichi,Kumadaki, Itsumaro
, p. 4782 - 4786 (2007/10/02)
In the presence of aluminium chloride, 1,1,1-trifluoro-2-hexanone reacts as an enophile with several allyl compounds to give trifluoromethylated homoallyl alcohols. α,α,α-Trifluoroacetophenone reacts similarly with aliphatic allyl compounds, but its react
