110245-50-6Relevant articles and documents
Enhancing thermal stability in aminopyridine iron(II)-catalyzed polymerization of conjugated dienes
Jing, Chuyang,Wang, Liang,Zhu, Guangqian,Hou, Hongbin,Zhou, Li,Wang, Qinggang
, p. 4019 - 4026 (2020)
A library of well-defined aminopyridine iron(II) precatalysts with a tertiary amine moiety have been prepared and serve as highly efficient precatalysts for polymerization of isoprene and other biobased conjugated dienes, delivering the corresponding poly
Cobalt carbonyl-based catalyst for hydrosilylation of carboxamides
Dombray, Thomas,Helleu, Camille,Darcel, Christophe,Sortais, Jean-Baptiste
supporting information, p. 3358 - 3362 (2013/12/04)
The cobalt carbonyl [Co2(CO)8] complex is employed as a useful catalyst for the reduction of tertiary amides to the corresponding tertiary amines using 1,1,3,3-tetramethyldisiloxane (TMDS) and poly(methylhydrosiloxane) (PMHS) as silane reagents under thermal (100 °C) or photo-assisted conditions (UV, 350 nm at room temperature). Of particular interest, a low catalytic amount (0.5 mol%) of [Co2(CO)8] is used to perform the reaction with 2.2 equiv. of PMHS at 100 °C for 3 h. This reaction is the first example of a cobalt-catalyzed hydrosilylation of amides. Copyright
Effects of a side chain aromatic ring on the reactivity of copper(I) complexes with dioxygen
Shimazaki, Yuichi,Nogami, Takeo,Tani, Fumito,Odani, Akira,Yamauchi, Osamu
, p. 3859 - 3862 (2007/10/03)
Stabilization of the bis(μ-oxo)dicopper(III) intermediate is achieved by using a bidentate N-donor ligand with pendent indole rings: N,N-bis[(3-indolyl)methyl]N-[(2′-pyridyl)methyl]amine (BIP). The intermediate decomposes to give products arising from N-dealkylation and a product with a spiro ring composed of two indole rings (see scheme). This latter product probably results from a radical-coupling reaction.
