110247-86-4

Upstream product

• 614-73-3 1-ethoxy-2-iodobenzene 
• 464-72-2 tetraphenylethane-1,2-diol 
• 6290-24-0 ethyl 2-ethoxybenzoate 

Downstream Products

• 110247-02-4 2-benzhydryl-phenetole 
• 102478-53-5 2-(α-chloro-benzhydryl)-phenetole 
• 114165-00-3 2-ethoxy-trityl 
• 102751-74-6 (2-ethoxy-phenyl)-methoxy-diphenyl-methane 
• 103158-44-7 (2-ethoxy-phenyl)-phenoxy-diphenyl-methane 
• 116153-46-9 1,2-bis-(2-ethoxy-phenyl)-1,1,2,2-tetraphenyl-ethane 
• 103404-29-1 bis-[(2-ethoxy-phenyl)-diphenyl-methyl]-peroxide 

Relevant academic research and scientific papers

Sodium-Ketyl Radical Anions by Reverse Pinacol Reaction and Their Coupling with Iodoarenes

Transition-metal-free C-C bond formation between aryl iodides and pinacols is presented. Pinacols are readily transformed by deprotonation with NaH to their Na-pinacolates. C-C-bond homolysis at room temperature generates in situ the corresponding Na-ketyl radical anions which react with various aryl iodides in a homolytic aromatic substitution reaction to form tertiary Na-alcoholates. Protonation eventually provides tertiary alcohols in an unprecedented route.