464-72-2Relevant articles and documents
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Jerumanis,Martel
, p. 1716,1719 (1970)
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Visible-Light Induced Photofixation of CO2 into Benzophenone Catalyzed by Colloidal CdS Microcrystallites
Kanemoto, Masashi,Ankyu, Hirofumi,Wada, Yuji,Yanagida, Shozo
, p. 2113 - 2114 (1992)
Photocatalytic fixation of CO2 into benzophenone has been achieved under λ > 400-nm light irradiation of a CO2-saturated DMF solution of colloidal CdS microcrystallites as photocatalysts, triethylamine as a sacrificial electron donor, and benzophenone yielding benzilic acid with benzhydrol and benzopinacol.
Chemical reactions of benzophenone photoirradiated in 1,2-polybutadiene
Barboiu, Virgil,Avadanei, Mihaela Iuliana
, p. 170 - 179 (2011)
The photolysis of benzophenone (BP) in 1,2-polybutadiene (1,2PB) was studied at low radiation intensity in order to clarify some aspects of BP photochemistry and of 1,2PB photocrosslinking. The expected primary photoreactions of hydrogen abstraction and c
Interaction between alkali metal aromatic ketone radical anions and the chlorides of lithium and magnesium in solution. A case of a carbon-carbon bond strengthening through complex formation
Micha-Screttas, Maria,Heropoulos, Georgios A.,Steele, Barry R.
, p. 2685 - 2690 (1999)
The interaction between lithium, sodium and potassium salts with the pre-formed radical anions of benzophenone, 2-methylbenzophenone, 2,4,6-trimethylbenzophenone or fluorenone, and lithium or magnesium chlorides has been studied by nuclear magnetic resona
Den Hollander et al.
, p. 211,212 (1977)
Neckers,Colenbrander
, p. 5045 (1968)
Pitts et al.
, p. 3606 (1964)
Photochemical Cycloaddition of Benzophenone to 7-Methylenetetracyclo2,8.04,6>octan-3-one and its Alcohol Derivative
Nitta, Makoto,Kuroki, Toshio,Sugiyama, Hiroshi
, p. 378 - 380 (1980)
Irradiation of benzophenone with 2,4-dimethyl- or 1,2,4-trimethyl-7-methylenetetracyclo2,8.04,6>octan-3-one affords oxetans (3a) and (3b), respectively, while irradiation with the alcohol derivative (2) affords a rearranged product (5) in addition to an oxetan.
Billet,Smith
, p. 4108 (1968)
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Bowen,de la Praudiere
, p. 1503,1504 (1934)
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Ultrasound effects on the photopinacolization of benzophenone
Gaplovsky,Gaplovsky,Toma,Luche
, p. 8444 - 8447 (2000)
Ultrasonic irradiation is able to modify the course of several photochemical reactions, especially bimolecular, proceeding via triplet states. These effects were illustrated in the study of benzophenone photopinacolization in ethanol. The rates and yields increase when sonication is applied simultaneously to UV irradiation. An explanation is based on a 2-fold effect: (i) light-absorbing transient species undergo sonolytic decomposition, making the photoconversion more efficient, and (ii) sonication induces the triplet state quenching, as shown by Stern-Volmer plots from experiments run in the presence of naphthalene, probably due to the easier collisional deactivation processes favored by the homogeneous distribution of the activated species.
Visible-Light Induced Photocatalysis of Partially Fluorinated Poly(p-phenylene) and Related Linear Phenylene Derivatives
Maruo, Katsuyo,Yamada, Kazuyori,Wada, Yuji,Yanagida, Shozo
, p. 1053 - 1064 (1993)
As a partially fluorinated poly(p-phenylene) derivative, yellow powder PF-PPP-n with high solubility in organic solvents was prepared as a mixture of oligomers by nickel-catalyzed polycondensation of the Grignard reagent from 1-bromo-2,4,6-trifluorobenzene.PF-PPP-n shows photocatalytic activity for reduction of water to H2, carbonyl compounds to alcohols, and dimethyl maleate and fumarate to the succinate under visible-light (λ > 400 nm) irradiation in the presence of triethylamine as a sacrificial electron donor.The photocatalysis was compared with those of other related fluorinated linear aromatics such as perfluorinated poly(p-phenylene sulfide) (F-PPS-n), perfluorinated poly(p-phenylene) (F-PPP-n).Their spectral characteristics and photocatalysis are discussed on the basis of the semiempirical molecular orbital calculations.
Photodriven Dehydrogenative Homocoupling of Benzylic C-H Bonds Forming Strained C-C Bonds
Ishida, Naoki,Son, Mingon,Kawasaki, Tairin,Ito, Misato,Murakami, Masahiro
supporting information, p. 2067 - 2070 (2021/10/14)
A photoinduced dehydrogenative homocoupling reaction of alkylarenes is reported. Gaseous hydrogen is evolved as the sole byproduct and neither oxidants nor hydrogen acceptors are required. The present reaction offers an environmentally benign and atom-economical means for forming sterically strained C-C single bonds. It also gives a remarkable example of photodriven reactions overcoming a considerable rise in energy.
Tunable System for Electrochemical Reduction of Ketones and Phthalimides
Chen, Gong,Qiao, Tianjiao,Wang, Yaxin,Zhang, Jian,Zhao, Jianyou
supporting information, p. 3297 - 3302 (2021/10/14)
Herein, we report an efficient, tunable system for electrochemical reduction of ketones and phthalimides at room temperature without the need for stoichiometric external reductants. By utilizing NaN3 as the electrolyte and graphite felt as both the cathode and the anode, we were able to selectively reduce the carbonyl groups of the substrates to alcohols, pinacols, or methylene groups by judiciously choosing the solvent and an acidic additive. The reaction conditions were compatible with a diverse array of functional groups, and phthalimides could undergo one-pot reductive cyclization to afford products with indolizidine scaffolds. Mechanistic studies showed that the reactions involved electron, proton, and hydrogen atom transfers. Importantly, an N3/HN3 cycle operated as a hydrogen atom shuttle, which was critical for reduction of the carbonyl groups to methylene groups.
A convenient pinacol coupling of diaryl ketones with B2pin2viapyridine catalysis
Jo, Junhyuk,Kim, Seonyul,Choi, Jun-Ho,Chung, Won-Jin
supporting information, p. 1360 - 1363 (2021/02/22)
A convenient, pyridine-boryl radical-mediated pinacol coupling of diaryl ketones is developed. In contrast to the conventional pinacol coupling that requires sensitive reducing metal, the current method employs a stable diboron reagent and pyridine Lewis base catalyst for the generation of a ketyl radical. The newly developed process is operationally simple, and the desired diols are produced with excellent efficiency in up to 99% yield within 1 hour. The superior reactivity of diaryl ketone was observed over monoaryl carbonyl compounds and analyzed by DFT calculations, which suggests the necessity of both aromatic rings for the maximum stabilization of the transition states.