110307-03-4Relevant academic research and scientific papers
Synthesis of N-Formyl-2-benzoyl Benzothiazolines, 2-Substituted Benzothiazoles, and Symmetrical Disulfides from N-Phenacylbenzothiazolium Bromides
Sahoo, Subas Chandra,Pan, Subhas Chandra
, p. 6208 - 6212 (2019/08/21)
An unusual aerobic hydrolysis-cascade reaction has been developed with N-phenacylbenzothiazolium bromides by treatment with organic and inorganic base. The corresponding N-formyl-2-benzoyl benzothiazoline and 2-substituted benzothiazole products were obta
A removable functional group strategy for regiodivergent Wittig rearrangement products
Alam, Md Nirshad,Lakshmi,Maity, Pradip
supporting information, p. 8922 - 8926 (2018/12/10)
[1,2] and [2,3] Wittig rearrangements are competing reaction pathways, often leading to uncontrollable product distribution. We employ a single removable functional group to fulfill the dual role of attaining a reversible [2,3] and stabilizing radical int
ORTHO-LITHIATION OF 2-(BENZOTHIAZOL-2-YLTHIO)PYRIDINE. PREPARATION OF 2,3-DISUBSTITUTED PYRIDINES
Katritzky, Alan R.,Aurrecoechea, Jose M.,Miguel, Luis M. Vazquez de
, p. 427 - 436 (2007/10/02)
2-(Benzothiazol-2-ylthio)pyridine undergoes lithiation exclusively at the 3-position.The products of reaction with electrophiles of the lithiated species undergo sulfide cleavage to give 3-substituted 2-alkylthiopyridines and/or 3-substituted pyridine-2-thiones.
Carbanions Derived from 2-Alkylthiobenzothiazoles. A Novel α-Lithiomethyl Mercaptan Synthon for Mercaptomethylation.
Katritzky, Alan R.,Aurrecoechea, Jose M.,Vazques de Miguel, Luis M.
, p. 769 - 774 (2007/10/02)
2-Methylthiobenzothiazole readily gives a methyl group lithio derivative which reacts cleanly with electrophiles.The products are conveniently converted into the corresponding thiols by BuLi at -78 deg C, and this sequence thus provides a convenient two-step mercaptomethylation procedure for alkyl halides, aldehydes, and ketones.
