110324-86-2Relevant academic research and scientific papers
Bio-specific and bio-orthogonal chemistries to switch-off the quencher of a FRET-based fluorescent probe: Application to living-cell biothiol imaging
Egloff,Jacques,Nothisen,Weltin,Calligaro,Mosser,Remy,Wagner
, p. 10049 - 10051 (2014)
We report the first molecular system that is responsive to both a bio-specific and a bio-orthogonal stimulus. This dual activation process was applied to the design of a biothiol-specific FRET-based fluorescent probe that could be turned-on via an original concept of quencher bleaching. This journal is the Partner Organisations 2014.
Alkylation of the α-amino C-H bonds of anilines photocatalyzed by a DMEDA-Cu-benzophenone complex: reaction scope and mechanistic studies
Abadie, Baptiste,Jonusauskas, Gediminas,McClenaghan, Nathan D.,Toullec, Patrick Y.,Vincent, Jean-Marc
supporting information, p. 5800 - 5805 (2021/07/12)
The Cu(ii) complex1incorporating a BP chromophore is a highly active and chemoselective photocatalyst for the alkylation of α-amino C-H bonds of anilines. The reaction was shown to proceed with a broad substrate scope in the absence of additives. Extensive mechanistic studies were performed, in particular using transient absorption spectroscopy, and spectroscopic signatures of key intermediates were identified in the conditions of catalysis. Finally, the ability of1to act as a multitask catalyst was showcased by conducting multi-component CuAAC and olefin hydroalkylation reactions in one-pot.
The coupling of tertiary amines with acrylate derivatives via visible-light photoredox catalysis
Dai, Xiaojun,Cheng, Dongping,Guan, Baochuan,Mao, Wenjuan,Xu, Xiaoliang,Li, Xiaonian
, p. 7212 - 7219 (2014/08/18)
Catalyzed by Ru(bpy)3(BF4)2, the photoredox coupling of tertiary amines with acrylate derivatives including Baylis-Hillman adducts under visible light irradiation was successfully established. The scope of the substrates w
