110328-13-7Relevant articles and documents
MECHANISM OF THE ADDITION OF TRIBUTYLTIN IODOACETATE TO ALKENES
Degueil-Castaing, M.,Jeso, B. De,Kraus, G. A.,Landgrebe, K.,Maillard, B.
, p. 5927 - 5930 (1986)
The mechanism of the formation of lactones by free radical additions of tri-n-butyltin iodoacetate to alkenes occurs through a two-step process: a homolytic addition of the ester (addition of .CH2-CO2SnBu3, iodine transfer), followed by a fast ionic cyclization with elimination of tri-n-butyltin iodide.