110339-24-7Relevant academic research and scientific papers
α-Chlorination and Carbonylolefination: Synthesis of Phenyl 1-Chloro-1-alken-1-yl Selenides (Chlorovinyl Phenyl Selenides)
Coutrot, P.,Grison, C.,Youssefi-Tabrizi, M.
, p. 169 - 170 (2007/10/02)
The lithium derivatives prepared from diethyl phenylselenomethanephosphonate with n-butyllithium at low temperature react with carbon tetrachloride to give the corresponding α-chlorinated phosphonate and trichloromethyllithium.The latter deprotonates the α-chlorinated phosphonate in situ to give a new lithio derivative which reacts with carbonyl compounds.These different steps take place in one pot and lead to chlorovinyl phenyl selenides, a novel class of selenocompounds.
